A case of alkylidyne-imine metathesis

Reactions between imines and tungsten alkylidyne complexes are studied. The trianionic pincer ligand supported alkylidyne [tBuOCO]WCC(CH3)3(THF)2 (1) reacts with N-(R)-1-phenylmethanimine (PMI-R, R = Me, Ph, Bn, and TMS) yielding [tBuOC(H)O]W(eta 2-tBuC0000000000000000000000000000000000000000000000000000111111111111111000000000000000000011111111111111100000000000000000001111111111111110000000000000000000000000000000000000000000000000000CPh)N(R) (4-R), products from metathesis reaction. In contrast, the non-pincer alkylidyne (tBuO)3WCC(CH3)3 does not react with PMI-R imines. Reactions between imines and tungsten alkylidyne complexes are studied.