Dispersion of ultrastable crown-ether-functionalized triphenylamine and pyrene-linked porous organic conjugated polymers with single-walled carbon nanotubes as high-performance electrodes for supercapacitors
POLYMER CHEMISTRY(2023)
摘要
We have successfully synthesized a new type of porous organic polymer (POP), called CE-Py POP, which incorporates both crown ether and pyrene using a [4 + 4] Schiff base condensation method. The CE-Py POP structure has been confirmed through various analytical techniques and has exhibited excellent thermal stability and char yield, with a Td10 value of 416 degrees C and 67 wt%, respectively. To create suitable materials for supercapacitor devices, we blended CE-Py POP with single-walled carbon nanotubes (SWCNTs) through pi-pi interactions to form a CE-Py POP/SWCNT nanocomposite. In galvanostatic charge-discharge (GCD) experiments, the CE-Py POP/SWCNT nanocomposite exhibited an impressive specific capacitance value reaching 346 F g-1 and demonstrated exceptional capacitance retention, maintaining 97.6% of its original capacitance even after more than 2000 cycles. A CE-Py POP/SWCNT nanocomposite was prepared through pi-pi interactions between CE-Py POP and SWCNT. During GCD experiments, this nanocomposite exhibited a remarkable specific capacitance of 346 F g-1 and outstanding capacitance retention.
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关键词
porous organic conjugated polymers,crown-ether,pyrene-linked,single-walled,high-performance
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