Characterizing the water-rock interactions and groundwater flow processes in the Paleozoic to Cenozoic strata aquifer systems with contrasting mineralogy at basin scale: Qingyi river, east China

This study aims to identify water-rock interaction and groundwater flow processes in aquifer systems with contrasting mineralogy at the basin scale. Investigations have been carried out using major ion geochemistry and environmental isotopes (& delta;2H and & delta;18O of water, & delta;13C values, 87Sr/86Sr ratios, and 14C activities) within aquifers with contrasting mineralogy in the Qingyi river basin (QRB, east China) composed of marine carbonate and continental granitic sediments with successive strata during Paleozoic, Mesozoic and Cenozoic. Analysis of 95 rain, surface and groundwater, and 12 solid rock samples found that dissolution of limestone, silicate minerals, and evapotranspiration dominated the hydrogeochemical process in the lower, upper, and middle basin, respectively. The various major ion and 87Sr/86Sr ratios of groundwater in each aquifer suggest that local lithology minerals dissolution controls the water-rock equilibria in the groundwater system. The 87Sr/86Sr ratios are correlated with both major ion geochemistry and & delta;13C values, constraining the process of varying proportions of silicate and carbonate minerals dissolution. Percolating water from soils carrying dissolved CO2 plays an important role in controlling the hydrogeochemical processes in the groundwater system throughout the QRB. Inter-aquifer flow has been proved by the well correlated relations between 87Sr/86Sr ratios and & delta;13C values or/ and Sr/Na and Ca/Na ratios, as well as the irregular groundwater apparent 14C ages (1.78 to 8.52 kyr) with respect to position in the basin. Admixture ratios of 9-50% are derived from the groundwater in limestone aquifer. The rapid decrease in carbonate groundwater mixing ratio is accompanied by an increase in 87Sr/86Sr ratios, indicating that groundwater is derived Sr from silicate weathering and abundant carbon from the soils. Regional inter-aquifer flow occurs in the buried carbonate aquifers based on isotopic evidence, which could result in karstic groundwater leakage in the Wuhu cityside and should be given special attention.