Photocatalytic degradation of chlorpyrifos using Ag nanoparticles-doped g-C3N5 decorated with dendritic CdS.

In this work, g-C3N5/CdS dendrite/AgNPs nanocomposite was synthesized using a mixed method consisting of hydrothermal, ultrasonic and chemistry reduction with sodium borohydride. The characterization of the as-prepared nanocomposite was done using infrared spectroscopy, X-ray, scanning electron microscopy, transmission electron microscopy, BET, and DRS methods was performed. The DRS results showed that the g-C3N5/CdS dendrite/AgNPs nanocomposite nanocomposite has a band gap of 1.08 eV. This band gap indicates the good capability of this nanocomposite as a photocatalyst. Accordingly, the photocatalytic degradation of chlorpyrifos (CPS) in was performed in an aqueous solution of the synthesized nanocomposite. The results showed that almost 95.3% of this poison, a concentration of 50 mg L-1 was degraded in the presence of 0.05 g L-1 of nanocomposite at pH = 5 in a 60 min. Hydroxide radicals and holes play a significant role in the photocatalytic process. The reusability of the nanocomposite with excellent performance in the degradation of photocatalytic toxins caused by the reduction in the electron-hole recombination and the high surface area of the nanocomposite are among the unique features of this work.