Hydrazine sulfonic acid, NH2NHSO3H, the bigger sibling of sulfamic acid.

Tobias Rennebaum,David van Gerven,Sean Sebastian,Mathias Wickleder

Chemistry (Weinheim an der Bergstrasse, Germany)（2023）

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Abstract

The reaction of hydrazine hydrate, N2H4·H2O, and SO3 leads to hydrazine sulfonic acid. The structure elucidation reveals the zwitteranionic nature of the compound according to NH3-NH-SO3. With the barium salt Ba[NH2NH(SO3)]2(H2O) a first salt of hydrazine sulfonic acid has been prepared. The compounds were characterized by vibrational spectroscopy, DFT calculations and thermal analyses.

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