Self-assembly construction of 1D carbon nitride nanotubes and cobalt-modified for superior photocatalytic degradation of sulfonamide antibiotics

In the present work, a cobalt-doped carbon nitride nanotubes (Co-CNt) was synthesized via self-assembly process. Contributed to the narrow band gap, enlarged specific surface area and abundant active sites, Co-CNt has excellent photoelectric properties and superior performance than pristine CN in sulfisoxazole (SIZ) degradation under blue light irradiation, which achieved 100% removal within 40 min. Meanwhile, the system not only exhibited practical applicability by efficiently degrading SIZ, but also generating high levels of H2O2. Moreover, the Co-CNt/visible light system shows superior operability over a wide pH range, micro-concentration contaminants, various anions, water matrices and other sulfonamides with promising catalytic stability and applicability. The contribution of RSs in the degradation process were elucidated based on radical scavenging and spin-trapped tests, clarifying that O2·- and h+ majorly dominated the process. In addition, 4 probable degradation pathways of SIZ were provided and the generated intermediates’ toxicity were evaluated. Overall, this study successfully synthesized a self-assembled 1D tubular photocatalyst with Co-doped and demonstrated the potential Co-CNt/visible light system for environmental remediation, providing a promising approach for the development of photocatalysis.