An Advanced Optimization Method to Minimize the Detection Limit of Liquid Scintillation Counter to Measure Low-Level Tritium Activity in Groundwater

In arid regions, the tritium concentration in groundwater is typically very low and often falls below the minimum detectable activity (MDA) of the conventional liquid scintillation counter (LSC). Therefore, to measure the tritium activity concentration, it is necessary to lower the detection limit so that the scintillation counter can detect it. In the present study, several methods are discussed which are effective at lowering the detectable activity of tritium. One of these methods is to enrich the tritium activity concentration by ten- to fortyfold of the initial concentration of the tritium. Twelve spiked samples with known amounts of tritium, five with high concentrations and seven with low concentrations, were enriched by the electrolysis process. The results indicated that enriching the tritium levels in groundwater lowers the MDA value. Other methods are minimizing background radiation using low-background materials for sample containers, increasing the measurement efficiency of the scintillation counter and counting time, and shielding the sample from environmental radiation using the shutter option in LSC. Moreover, reducing the number of interfering contaminants in the sample can lower the uncertainty in measuring the tritium concentration in the water sample, which is beneficial for detecting low-level tritium in water to ensure public health and safety.