Four- and Three-coordinate Planar Iron(II) Complexes Supported by Bulky Organosilyl Ligands

Reon Ishii,Minesato Nakagawa,Yoshimasa Wada,Yusuke Sunada

Dalton Transactions（2023）

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摘要

The ligand exchange reaction of (THF)2Fe[Si(SiMe3)3]2 with 2 equivalents of an N-heterocyclic carbene (NHC) led to the formation of the square-planar iron(II) complex with trans-oriented –Si(SiMe3)3 ligands. Conversely, the introduction...

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