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Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries

D. Pukazhselvan,Carlos M. Granadeiro,Francisco J.A. Loureiro,Aliaksandr L. Shaula,Sergey M. Mikhalev,Gil Gonçalves,Duncan Paul Fagg

Electrochimica Acta（2023）

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Abstract
•Nanorod shaped MIL-88B(Fe) and MIL-100(Fe) were tested as anodes for li ion batteries.•Overall, MIL-88B(Fe) exhibits higher capacity and lesser resistance than MIL-100(Fe).•Degradation and loss of Fe over cycles is found only in the MIL-88B(Fe) based electrode.•Li diffusion remains unaffected despite the degradation issue in MIL-88B(Fe).
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Key words
Secondary batteries, Metal organic frameworks, Nanomaterials, Impedance, Microstructure
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