Water quality at Chaco Culture National Historical Park and the potential effects of hydrocarbon extraction

Study region: Chaco Culture National Historical Park (CCNHP) is in the San Juan Basin of northwestern New Mexico, U.S.A. Its only water supply is in Gallup Sandstone aquifer, stratigraphically surrounded by layers long targeted for oil and natural gas extraction. Study focus: To assess groundwater flow direction, age, mixing between aquifers, and whether hydrocarbons extraction may affect water quality, we completed a geochemical groundwater sampling campaign. Groundwater at 11 sites was analyzed for major ions, hydrocarbon associated volatile organic carbon (VOC) compounds, noble gases, and the isotope systems delta H-2, delta O-18, Sr-87/Sr-86, delta C-13, and C-14. New hydrological insights for the region: Results demonstrate that all sampled groundwaters are exceedingly old and geochemically evolved, with a median C-14 age of similar to 41,000 years before present and a north flowing path. Three lines of evidence suggest mixing between aquifers through relatively impermeable shale units and mixing with hydrocarbons: 1) noble gases are fractionated likely through mixing with connate water expelled during hydrocarbon genesis; 2) several wells-including the park's main supply well-contained trace amounts of hydrocarbon related VOC compounds; and 3) major ion analysis shows mixing trends between aquifers. We hypothesize that cross-aquifer mixing may be facilitated through the region's numerous hydrocarbon related boreholes. Whether our findings are the result of oil and gas extraction or represent the natural state of the aquifers will require more research.