Stripping Enhanced Distillation-A Novel Application in Renewable CO2 to Dimethyl Ether Production and Purification

The transition towards a CO2 neutral industry is currently spurring many new developments regarding processes for the conversion of CO2, or CO2-rich streams, into platform molecules such as methanol and dimethyl ether (DME). New processes give rise to new separation challenges, as well as novel opportunities for joint optimization of reaction and separation. In this context, the separation of CO2 and DME can be performed very efficiently using the newly developed concept of stripping enhanced distillation (SED). SED is a distillation process that utilizes an additional stripping component (clearing gas) to promote the separation in the column. SED benefits from the utilization of the feedstock components as a clearing gas that can afterwards be recycled back to the conversion unit with the vapor distillate. Strongly improving the separation performance in the column, this approach also removes the need for external stripping mediums and, in addition, this recycling approach may significantly reduce the demand on the conversion unit upstream of SED. The benefits of using SED are demonstrated for two different processes for DME synthesis: (i) CO2-DME separation after the sorption enhanced DME synthesis (SEDMES) process, using hydrogen as clearing gas, and (ii) CO2-DME separation after direct DME synthesis via dry reforming (DIDR), using methane as a clearing gas. For the different cases, it is shown that, with minimal adaptations, the energy consumption for distillation is reduced by 20-30%, while product losses are minimized at the same time.