A study for polymer-based passivation mechanism: Insights of island-growth crystallization and carrier dynamic in perovskite films
JOURNAL OF ALLOYS AND COMPOUNDS(2023)
摘要
Polymer has been widely used for modifications in perovskite films. However, its comprehensive and complex mechanism is still lack of in-depth research. This work presents the possible mechanism for crystal growth in perovskite films under passivation circumstance. Through the crystallization and carrier dynamics analysis we establish an island-crystal growth model with low concentration precursor solution, it predicts that the curve of additive weight ratio versus film performance will reach a peak value and then decline to a mediocre level. We further set several experiment groups and test this hypothesis with a series of characterizations. For the optoelectronic performance, passivation enhances the photosensitivity (I-light/I-dark) to similar to 1020%. The aging test under an elevated relative humidity (85%) demonstrates the passivated devices extend the lifetime to 96 h, which is 3 times higher than the reference group. In addition, the encapsulated group shows a really stable performance in 240 h storage, indicating polymer passivation has a great potential for suppressing ion migration effect in the perovskite material.
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关键词
Polymer passivation,Island-growth crystallization,Carrier dynamic,Perovskite films,Reduced grain boundary density
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