Investigations on structural, photoluminescent, and photometric properties of poly(vinyl alcohol)-capped Mn doped-ZnO nanoparticles for white light emission

In this paper, luminescent Mn-doped ZnO nanoparticles (NPs) and poly(vinyl alcohol) (PVA) capped Mn-doped ZnO nanocomposite materials were successfully synthesized by the chemistry route. The studied results indicate that the diffraction peaks of Mn-doped ZnO NPs (2, 4, and 7% Mn) are slightly shifted to the lower 2 & theta; degree angle compared to undoped-ZnO NPs. In contrast, PVA capped Mn-doped ZnO nanocomposite shows a systematic shift of X-ray diffraction (XRD) peaks at larger diffraction angles. These samples fluoresce strongly in the visible wavelength of 380-700 nm. The near-infrared (NIR) emission bands in the 740 nm-1100 nm range are due to the shift of XRD peaks diffraction and the transition between defect states within the ZnO crystal. Photometric and chromatic parameters of PVA capped-2%Mn doped-ZnO NPs are CIE (x, y) & AP;(0.3769, 0.3987), CCT & AP;4238 (K), Duv = 0.0110, CRI (Ra) = 80, CQS = 84, LER = 164 (lm/Wotp), and S/P ratio = 1.70. Luminescent PVA capped ZnO NPs possess CIE (x, y) & AP;(0.3598, 0.3748), CCT & AP;4592 (K), Duv = 0.0057, CRI (Ra) = 85, CQS = 87, LER = 207 (lm/Wotp), and S/P ratio = 1.83. The studied results indicate that these luminescent materials are suitable for developing a white light emission layer in the structure of light-emitting devices.