Boryl Radical-Promoted Deoxygenative Alkylation of Benzyl Acetates
SYNTHESIS-STUTTGART(2023)
摘要
Deoxygenative alkylation of benzyl alcohols was realized by using acetate as the alcohol activation group. The C-O bond homolysis is achieved by a boryl radical-promoted beta-scission process. The strategy is amenable to a variety of benzyl alcohols, including primary, secondary, and more challenging tertiary alcohols. The synthetic practicability was demonstrated by a gram-scale one-pot reaction.
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关键词
deoxygenative alkylation, C-O bond activation, reduction, boryl radical
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