Compressible, anti-freezing, and ionic conductive cellulose/polyacrylic acid composite hydrogel prepared via AlCl3/ZnCl2 aqueous system as solvent and catalyst
International journal of biological macromolecules(2023)
Abstract
From the perspective of environmental sustainability, introducing cellulose into ionic conductive hydrogel is an inevitable trend for the development of flexible conductive materials. We report a double-network cellulose/ polyacrylic acid (Cel/PAA) composite hydrogel based on the dissolving of cellulose by AlCl3/ZnCl2 aqueous system. The Cel/PAA composite hydrogel consists of rigid cellulose chains and flexible polyacrylic acid, which synergistically realize the improvement of the mechanical properties. The AlCl3/ZnCl2 aqueous system not only serves as the green solvent for cellulose, but also the Al3+ and Zn2+ metal ions can be served as a catalyst to activate the initiator for polymerization of acrylic acid. Compared with pure cellulose hydrogel, the compression strain of the Cel/PAA composite hydrogel was significantly improved to 80 %, and its conductivity increased by 28.1 %. In addition, its compression stress was enhanced over 2 times than pure PAA hydrogel. The Cel/PAA composite hydrogel exhibits excellent anti-freezing (-45 degrees C), weight retention (90 %), and conductivity (2.70 S/ m) properties, still maintaining transparency and storage stability in the extreme environment. This work presents a facile strategy to develop an ionic conductive cellulose-based composite hydrogel with good conductivity and mechanical properties, which shows potential for the application fields of flexible sensors and 3D-printing functional materials.
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Key words
Cellulose ionic conductive hydrogels,Rapid polymerization,Composite hydrogel,AlCl3/ZnCl2
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