Bioinspired Hierarchical Multi-Protective Membrane for Extreme Environments via Co-Electrospinning-Electrospray Strategy

SMALL(2024)

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Abstract
Extreme environments can cause severe harm to human health, and even threaten life safety. Lightweight, breathable clothing with multi-protective functions would be of great application value. However, integrating multi-protective functions into nanofibers in a facile way remains a great challenge. Here, a one-step co-electrospinning-electrospray strategy is developed to fabricate a superhydrophobic multi-protective membrane (S-MPM). The water contact angle of S-MPM can reach up to 164.3 degrees. More importantly, S-MPM can resist the skin temperature drop (11.2 degrees C) or increase (17.2 degrees C) caused by 0 degrees C cold or 70 degrees C hot compared with pure electrospun membrane. In the cold climate (-5 degrees C), the anti-icing time of the S-MPM is extended by 2.52 times, while the deicing time is only 1.45 s due to the great photothermal effect. In a fire disaster situation, the total heat release and peak heat release rate values of flame retarded S-MPM drop sharply by 24.2% and 69.3%, respectively. The S-MPM will serve as the last line of defense for the human body and has the potential to trigger a revolution in the practical application of next-generation functional clothing. A superhydrophobic multi-protective membrane is achieved by the one-step co-electrospinning-electrospray (Co-ESS) strategy to protect human life and health in extreme environments.image
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Key words
electrospinning,electrospray,flame-retardants,micro-nanoscale,multi-protective,superhydrophobic
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