Synthesis of 2-Indolyl C -Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling.

Yan Xia,Yingjie Wang,Zhaolun Zhang,Tayyab Gulzar,Yuqi Lin,Jing Wang,Dapeng Zhu,Biao Yu

Organic letters（2023）

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摘要

The synthesis of neopetrosins A and C, two 2-indolyl -α-d-mannopyranosides, and their congeners has been realized via a direct Ni/photoredox-catalyzed reductive coupling of 3-methoxycarbonyl-2-iodo-1-indoles with pyranosyl bromides.

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