Thermoelectric and mechanical performances of ionic liquid-modulated PEDOT:PSS/SWCNT composites at high temperatures

Significant progress has been achieved for flexible polymer thermoelectric (TE) composites in the last decade due to their potential application in wearable devices and sensors. In sharp contrast to the exceptional increase in TE studies at room temperature, the mechanical performance of polymer TE composites has received relatively less attention despite the significance of the application of TE composites in high-temperature environments. The TE and mechanical performances of flexible poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)/single-walled carbon nanotube (PEDOT:PSS/SWCNT) composite films with an ionic liquid (IL) (referred to as “PEDOT:PSS/SWCNT-IL”) at high temperatures are studied in the present work. The fabricated composite films show increasing TE performance with increasing temperature and SWCNT content. The maximum value of the power factor reaches 301.35 μW m-1 K-2 at 470 K for the PEDOT:PSS/SWCNT-IL composite. Furthermore, the addition of the IL improves the elongation at break of the composites compared to the IL-free composites. This work promotes the advancement of flexible polymer TE composites and widens their potential applications at different temperature ranges.