Selective synthesis of germasila-adamantanes through germanium–silicon shift processes
CHEMICAL SCIENCE(2023)
摘要
The regioselective synthesis of germasila-adamantanes with the germanium atoms in the bridgehead positions is described starting from cyclic precursors by a cationic sila-Wagner-Meerwein (SWM) rearrangement reaction. The SWM rearrangement allows also a deliberate shift of germanium atoms from the periphery and within the cage structures into the bridgehead positions. This opens the possibility for a synthesis of germasila-adamantanes of defined germanium content and controlled regiochemistry. In the same way that sila-adamantane can be regarded as a molecular building block of elemental silicon, the germasila-adamantane molecules represent cutouts of silicon/germanium alloys.
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关键词
selective synthesis,germanium–silicon,germanium–silicon,germasila-adamantanes
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