Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru_0.35Fe_0.65(ptz)₆](BF₄)₂

Francisco Javier Valverde Muñoz, Ricardo Guillermo Torres Ramírez, Abhilash Ulhe,Elżbieta Trzop,Mousumi Dutta,Chinmoy Das,Pradip Chakraborty,Éric Collet

CrystEngComm（2023）

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摘要

Spin-crossover materials exhibit thermal conversion of their electronic state from low to high spin, involving both intra- and inter-molecular structural reorganisations, eventually accompanied by symmetry breaking, within the crystal.

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ferroelastic phase transition,structural trapping,low-spin,high-symmetry

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Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru0.35Fe0.65(ptz)6](BF4)2

Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru_0.35Fe_0.65(ptz)₆](BF₄)₂