Co/CeO2/C composites derived from bimetallic metal-organic frameworks for efficient microwave absorption

CeO2, an n-type semiconductor material, has been widely used in microwave absorption (MA) due to its unique structural features such as oxygen vacancies and interstitial atoms. In this paper, Co/CeO2/C com-posites were prepared by a hydrothermal method followed by a pyrolysis process. The effect of different pyrolysis temperatures (650-950 degrees C) on the MA property of the composites was investigated. When the pyrolysis temperature was 850 degrees C, the Co/CeO2/C-850 composite exhibited outstanding MA behavior in the frequency range of 2-18 GHz, displaying a minimum reflection loss (RLmin) of -45.22 dB and an effective absorption bandwidth (EAB) of 4.61 GHz at a thin thickness of 1.75 mm. The MA performance of the Co/CeO2/C composites is mainly attributed to the dielectric loss due to interfacial polarization orig-inating from different interfaces and dipole polarization caused by the oxygen vacancies in CeO2. In addition, the introduction of Co nanoparticles not only provides the magnetic loss but also modulates impendence matching for the current magnetoelectric coupling system.