Linker engineering toward near-infrared-I emissive metal-organic frameworks for amine detection.
Dalton transactions (Cambridge, England : 2003)(2023)
Abstract
Herein, organic linker-based near-infrared-I (NIR-I) emissive metal-organic frameworks (MOFs), with a maximum emission peak at 741 nm, were synthesized linker engineering. By integration of stronger acceptor and donor groups into one linker, a significant bathochromic-shift is realized. This MOF exhibits great selectivity and sensitivity for aniline and -phenylenediamine detection. This finding provides new insights into the rational design of NIR-MOFs for sensing and related applications.
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Key words
near-infrared-i,metal-organic
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