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Alkylation of catechol with cyclohexene. Novel sterically hindered o -quinones and catechols

T. N. Kocherova,N. O. Druzhkov,K. A. Martyanov,A. S. Shavyrin,M. V. Arsenyev,T. I. Kulikova,E. V. Baranov,V. A. Kuropatov,V. K. Cherkasov

RUSSIAN CHEMICAL BULLETIN（2020）

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Abstract
A synthetic procedure for the preparation of sterically hindered catechols and o -quinones by the reaction of catechol with cyclohexene was developed. Novel cyclohexyl substituted catechols displayed remarkable stability during redox transformations and could be used as redoxactive ligands.
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Key words
o-quinones, catechols, redox-active ligands, alkylation, cyclohexene
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