Thin continuous membrane coating with high surface energy for comprehensive antifouling seawater distillation.

Membrane distillation (MD) has prominent advantages such as treating high-salinity wastewater with a low-grade thermal energy, high salt rejection, and zero discharge. However, organic fouling and mineral scaling are two major challenges for hydrophobic MD membranes when used for practical applications. Commonly, improving organic fouling- and mineral scaling-resistance require oppositely enhanced wetting properties of membrane, thus is difficult to simultaneously realize dual resistance with one membrane. Here, we proposed to use underwater thermodynamically stable high-surface-energy coating to modify the hydrophobic membrane with Janus structures comprising different surface energy. The underlayered structure meets the hydrophobicity requirements of the MD membrane, while the coating layer realizes dual resistance to organic and inorganic foulants. Theoretical analysis and experimental proof reveal that the membrane with the high-surface-energy coating layer outperforms the pristine one with approximately 10 times of longevity. This strategy provides a new way for the use of high-surface-energy materials in versatilely fouling-resistant MD process.