Photoinduced Mechanical Cloaking of Diarylethene-Crosslinked Microgels

The serial connection of multiple stimuli-responses in polymer architectures enables the logically conjunctive gating of functional material processes on demand. Here, a photoswitchable diarylethene (DAE) acts as a crosslinker in poly(N-vinylcaprolactam) microgels and allows the light-induced shift of the volume phase-transition temperature (VPTT). While swollen microgels below the VPTT are susceptible to force and undergo breakage-aggregation processes, collapsed microgels above the VPTT stay intact in mechanical fields induced by ultrasonication. Within a VPTT shift regime, photoswitching of the DAE transfers microgels from the swollen to the collapsed state and thereby gates their response to force as demonstrated by the light-gated activation of an embedded fluorogenic mechanophore. This photoinduced mechanical cloaking system operates on the polymer topology level and is thereby principally universally applicable. Mechanical cloaking in microgels: a diarylethene photoswitch is introduced as a co-crosslinker into PVCL microgels. Light-induced photoswitching of the diaryethene results in a phase-transition shift and thus changes the swelling status of microgels at a fixed temperature, rendering them differently reactive to mechanical force.image