Innovations in p-n type heterostructure composite materials (La 2 O 3 /CeO 2 ) for environmental contamination remediation: synthesis, characterization, and performance assessment

Biomass Conversion and Biorefinery(2023)

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摘要
The widespread presence of textile dye pollutants as byproducts in water bodies has raised serious concerns about the impact on the environment and human health. In this study, a nanocomposite material was made and its performance as a photocatalyst was looked at under different optimal conditions. The La 2 O 3 /CeO 2 nanocomposite was created at room temperature using a simple and cost-effective co-precipitation method. In this study, different characterization tools, such as XRD, FE-SEM, UV-Drs, XPS, FT-IR, PL, and EDS, were used to look at the nanoparticles’ structures, shapes, and optical properties. In the photocatalytic activity investigation, methylene blue (MB) dye was employed as a chosen pollutant, and illumination was delivered by a 450-Watt mercury vapor UV lamp. The La 2 O 3 /CeO 2 nanocomposite removed 93% of the methylene blue dye in 100 min, compared to pure La 2 O 3 and CeO 2 nanoparticles (NPs). When the catalyst concentration was optimized at 25 mg/L and the pH was set to 12, 93% of the methylene blue was degraded in 100 min. The recyclability studies also revealed that the La 2 O 3 /CeO 2 photocatalyst maintained an 84% degradation efficiency up to the fourth cycle, indicating that it is a stable and effective catalyst. Studies that used scavengers found that hydroxyl radicals were responsible for the breakdown of MB. Thus, La 2 O 3 /CeO 2 photocatalysts may be regarded as a viable option for degrading organic dye pollutants in aqueous solutions. Graphical Abstract
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关键词
environmental contamination remediation,la2o3/ceo2,composite materials,la2o3/ceo2
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