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NO 3 2- centers in synthetic hydroxyapatite

I. P. Vorona,S. S. Ishchenko,N. P. Baran,V. V. Rudko,I. V. Zatovskiĭ,N. A. Gorodilova,V. Yu. Povarchuk

Physics of the Solid State（2010）

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Abstract
The structure and properties of NO 3 2− paramagnetic complexes formed by γ-rays and UV irradiation in synthetic hydroxyapatite have been investigated using EPR spectroscopy. The formation of NO 3 2− centers under UV irradiation has been revealed for the first time. It has been found that NO 3 2− complexes in synthetic hydroxyapatite form two types of paramagnetic centers. Models of the centers have been proposed, their EPR spectroscopy parameters have been determined, and the influence of thermal annealing has been investigated. As the microwave power increases, the inversion of the EPR spectra has been observed.
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Key words
Electron Paramag Netic Resonance,Hydroxyapatite,Electron Paramag Netic Resonance Spectrum,Hyperfine Interaction,Electron Paramag Netic Resonance Signal
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