C sp 3 –H Bond Functionalization of α-Bromo Ketones for the Synthesis of α-Keto Thioamides Using Elemental Sulfur
Russian Journal of Organic Chemistry(2022)
摘要
An efficient metal- and additive-free synthesis of α-keto thioamides has been developed via sulfur oxidation of the C sp 3–H bond of α-bromo ketones with amines. This environmentally friendly strategy made it possible to synthesize a wide series of α-keto thioamides with broad functional group tolerance.
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关键词
α-keto thioamides,C3–H bond functionalization,α-bromo ketones,additive-free synthesis,green chemistry
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