Conductivity of Composites MeWO 4 –Al 2 O 3 (Me = Ca, Sr)
Russian Journal of Electrochemistry(2023)
Abstract
Composites (1 – x )MeWO 4 – x Аl 2 O 3 (Me = Ca, Sr) are synthesized by the solid-phase method. Their phase composition and thermodynamic stability are confirmed by the XRD and TG-DSC data, respectively. Their morphology is studied by the SEM-EDA method. The conductivity of composites is studied by the method of electrochemical impedance spectroscopy as a function of the temperature, the gas-phase oxygen pressure, and the content of added disperse Аl 2 O 3 . It is shown that composites (1 – x )MeWO 4 – x Аl 2 O 3 (Me = Ca, Sr) are ionic conductors and their conductivity is 4–12 times higher as compared with the corresponding tungstates.
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Key words
calcium tungstate,strontium tungstate,aluminum oxide,composite,heterogeneous doping,composite effect
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