Visible-Light-Induced Synthesis of Thioethers through Three-Component Reactions of a-Diazoesters, Thiols, and Cyclic Ethers
ASIAN JOURNAL OF ORGANIC CHEMISTRY(2023)
Abstract
Thioethers are important sulfur-containing compounds that have widespread application in organic synthesis, medicinal chemistry and materials science. Herein, a visible-light-mediated three-component reaction of a-diazoester, thiol, and cyclic ether leading to thioether has been developed at room temperature. Through this methodology, a variety of three-component coupling products with the introduction of the ring-opening of ether could be efficiently assembled under photocatalyst- and additive-free conditions.
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Key words
& alpha,-diazoesters,thioethers,thiols,three-component reaction,visible-light
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