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Thermal and Pyrolysis Kinetics Analysis of Glass Wool and XPS Insulation Materials Used in High-Rise Buildings

Fire(2023)

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摘要
This study investigates the kinetics data of glass wool (GW) and extruded polystyrene (XPS) insulation materials used in cladding systems using a systematic framework. The determination of appropriate kinetic properties, such as pre-exponential factors, activation energy and reaction orders, is crucial for accurately modelling the full-scale fire performance of insulation materials. The primary objective of this research is to extract thermal and kinetics data of XPS and GW insulation materials employed in high-rise buildings. To obtain these properties, thermogravimetric analysis (TGA) is conducted at four different heating rates: 5, 10, 15 and 20 K/min. The TGA results serve as the basis for determining the kinetic properties using a combination of model-free and model-based methods. The outcomes of this study are expected to be highly beneficial in defining the pyrolysis reaction steps and extracting kinetics data for fire modelling of such insulation materials. This information will enhance the understanding of the fire behaviour and performance of these materials during fire incidents, aiding in developing more accurate fire models and improving fire safety strategies for cladding systems in high-rise buildings.
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关键词
insulation materials,thermal degradation,pyrolysis,kinetics parameters,reaction steps,fire simulation
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