A Cd(II) MOF based on 5-ethoxyisophthalate and 1,3-bis(4-pyridyl)propane ligands with a twofold interpenetrated crystal structure showing room temperature phosphorescence
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES(2023)
摘要
A metal-organic framework (MOF) {[Cd(EtOI-PA)(bpp)(H2O)]center dot 2H(2)O}(n) (1) has been synthesized under basic hydrothermal conditions by using of 5- ethoxyisophthalic acid ( EtOIPAH(2)) and 1,3-bis( 4-pyridyl)propane ( bpp) as reagents for cadmium nitrate. Compound 1 was characterized by elemental analysis, single-crystal X-ray diffraction and UV/Vis spectroscopy. In 1, the bpp ligands extend the EtOIPA-Cd chains along the ab plane to form a 2-fold 3D interpenetrating network. Compound 1 emits blue phosphorescence at room temperature with a long lifetime of 4.2ms.
更多查看译文
关键词
cadmium complex, interpenetrating network, metal-organic framework, room temperature phosphorescence
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要