Research Progress of ZnIn₂S₄-Based Catalysts for Photocatalytic Overall Water Splitting

Photocatalytic overall water splitting in solar-chemical energy conversion can effectively mitigate environmental pollution and resource depletion. Stable ternary metal indium zinc sulfide (ZnIn2S4) is considered one of the ideal materials for photocatalytic overall water splitting due to its unique electronic and optical properties, as well as suitable conduction and valence band positions for suitable photocatalytic overall water splitting, and it has attracted widespread researcher interest. Herein, we first briefly describe the mechanism of photocatalytic overall water splitting, and then introduce the properties of ZnIn2S4 including crystal structure, energy band structure, as well as the main synthetic methods and morphology. Subsequently, we systematically summarize the research progress of ZnIn2S4-based photocatalysts to achieve overall water splitting through modification methods such as defect engineering, heterostructure construction, and co-catalyst loading. Finally, we provide insights into the prospects and challenges for the overall water splitting of ZnIn2S4-based photocatalysts.