Triphenylamine-Based Bis(β-Diketones) for Construction of Supramolecular Copper(II) Complexes
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY(2023)
Abstract
Two new bis(β-diketone) ligands based on triphenylamine have been prepared and crystallized. Treatment of 4,4′-diformyltriphenylamine with two phospholenes (2,2,2-trimethoxy-4,5-dimethyl-1,3,2-dioxaphospholene and 2,2,2-trimethoxy-4,5-diethyl-1,3,2-dioxaphospholene) afforded the bis(β-diketones) triphenylaminebis(2,4-pentanedione) (tpbaH 2 , 1 ); and triphenylaminebis(3,5-heptanedione) (tpbprH 2 , 2 ) as white solids. X-ray analysis of 1 and 2 shows that they are in the enol form. Also, their triphenylamine moieties have a chiral “propeller” shape; the centrosymmetric structures contain equal numbers of the two enantiomeric propellers. Reaction of 1 and 2 with [Cu(NH 3 ) 4 ] 2+ (aq) yielded dark-green solids. The Cu complex of 1 was insoluble in common solvents, but that of 2 , Cu 4 (tpbpr) 4 ( 3 ), is soluble in dichloromethane and chloroform. 3 is assigned the cyclic tetrameric structure Cu 4 (tpbpr) 4 based on ESI–MS and microanalytical data. This is similar to the copper(II) β-diketonate molecular squares reported previously from our group. Molecular modeling indicates that Cu 4 (tpbpr) 4 has Cu···Cu distances of ca. 21 Å, as compared to ca. 14 Å in the previous molecular squares. Graphical Abstract Crystal structures of two new bis(β-diketones) are reported, which are likely to form large supramolecular structures on reaction with metal ions such as Cu 2+ .
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Key words
complexes,copperii,triphenylamine-based
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