Experimental Study on the Preparation of Hydrogen-Rich Gas by Gasifying of Traditional Chinese Medicine Residue in a DFB Based on Calcium Looping

Using traditional Chinese medicine residue biomass as the raw material and industrial limestone as a carbon absorbent, this paper investigates the production of hydrogen-rich synthesis gas in a pilot-scale calcium looping dual fluidized bed (DFB) system. The study focuses on analyzing the distribution characteristics of temperature and pressure, as well as the operation and control methods of the DFB system. The effects of reaction temperature, material layer height (residence time), water vapor/biomass ratio (S/B), and calcium/carbon molar ratio (Ca/C) on gasification products are examined. The experimental results demonstrate that as the temperature (600-700 degrees C), S/B ratio (0.5-1.5), Ca/C ratio (0-0.6), and other parameters increase, the gas composition shows a gradual increase in the volume content of H-2, a gradual decrease in the volume content of CO, and an initial increase and subsequent decrease in the volume content of CH4. Within the range of operating conditions in this study, the optimal conditions for producing hydrogen-rich gas are 700 degrees C, an S/B ratio of 1.5, and a Ca/C ratio of 0.6. Furthermore, increasing the height of the material layer in the gasification furnace (residence time) enhances the absorption of CO2 by the calcium absorbents, thus promoting an increase in the volume content of H-2 and the carbon conversion rate in the gas.