Study on the different effects of aluminum doping on Fe-Mn and Ni-Mn based compounds as cathode material for sodium-ion batteries

Al-doped Fe-Mn and Ni-Mn based materials with P2-type layered structure has been synthesized and tested as a positive electrode material for rechargeable sodium batteries. The modification mechanisms of Al doping in Fe-Mn and Ni-Mn based materials have been discussed. The synthesized Al-doped Ni-Mn based material Na0.67Mn0.8Ni0.16Al0.04O2 delivers a reversible capacity of 135.1 mAh g-1, which corre-sponds to 92.1% of the initial capacity with excellent cyclability for 200 cycles. What's more, it can still remain a capacity of 96.2 mAh g-1 at a current density of 2000 mA g-1. When the voltage range increase to 1.5 - 4.3 V, its initial discharge capacity can reach 190.3 mAh g-1.(c) 2023 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.