Unravelling oxygen driven α to β phase transformation in tungsten
Scientific Reports(2020)
摘要
Thin films of β -W are the most interesting for manipulating magnetic moments using spin–orbit torques, and a clear understanding of α to β phase transition in W by doping impurity, especially oxygen, is needed. Here we present a combined experimental and theoretical study using grazing incidence X-ray diffraction, photoelectron spectroscopy, electron microscopy, and ab initio calculations to explore atomic structure, bonding, and oxygen content for understanding the formation of β -W. It is found that the W films on SiO 2 /Si have 13–22 at.% oxygen in A15 β structure. Ab initio calculations show higher solution energy of oxygen in β -W, and a tendency to transform locally from α to β phase with increasing oxygen concentration. X-ray absorption spectroscopy also revealed local geometry of oxygen in β -W, in agreement with the simulated one. These results offer an opportunity for a fundamental understanding of the structural transition in α -W and further development of β -W phase for device applications.
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