C sp3 -H Imination Using Arylazo Sulfone as a N Source: An Approach to Access Imines.
Organic letters(2023)
Abstract
An unprecedented C-H imination reaction using arylazo sulfones as the readily accessible and stable N source is reported. The synthetic virtues are demonstrated through mild conditions, simple operation, good air compatibility, and functional group tolerance, as well as suitability for gram-scale reaction. The resulting imines can be further converted to α-amino acids. The presented results shed light on an unusual usage of arylazo sulfones and will inspire novel experimental design by using arylazo sulfones as the N source.
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Key words
arylazo sulfone
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