Synthesis and characterization of cyclopropaosmabenzenes containing a fused σ-aromatic metallacyclopropene unit

Xiaoli Cheng,Qiang Cao,Yuhui Hua, Xu Cheng,Zhenwei Chu,Guomei He,Jiangxi Chen

Inorganica Chimica Acta（2023）

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摘要

•The cyclopropaosmabenzenes containing a metallacyclopropene unit were synthesized and characterized.•The σ-aromaticity and the π-aromaticity of the polycyclic cyclopropaosmabenzene are supported by experimental observations and theoretical calculations.

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关键词

Metallacycles,Aromaticity,Cyclopropaosmabenzene,Metallacyclopropene,Osmium

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