In situ synchrotron radiation diffraction study of the Li+ de/intercalation behavior in spinel LiNi0.5Mn1.5O4-δ
Chemical Engineering Journal(2020)
Abstract
•Oxygen content control of LiNi0.5Mn1.5O4 was achieved via a microwave annealing treatment;•The prepared non-stoichiometric LiNi0.5Mn1.5O4-δ material delivers excellent rate capability;•A solid-solution-like reaction in the prepared LiNi0.5Mn1.5O4-δ during cycling was deciphered.
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Key words
Spinel LiNi0.5Mn1.5O4,Cathode material,Rate capability,Oxygen vacancies,Structural evolution,In situ synchrotron radiation diffraction
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