Long-term stability in γ-CsPbI 3 perovskite via an ultraviolet-curable polymer network
Communications Materials(2021)
Abstract
Black-colored (α, γ-phase) CsPbI 3 perovskites have a small bandgap and excellent absorption properties in the visible light regime, making them attractive for solar cells. However, their long-term stability in ambient conditions is limited. Here, we demonstrate a strategy to improve structural and electrical long-term stability in γ-CsPbI 3 by the use of an ultraviolet-curable polyethylene glycol dimethacrylate (PEGDMA) polymer network. Oxygen lone pair electrons from the PEGDMA are found to capture Cs + and Pb 2+ cations, improving crystal growth of γ-CsPbI 3 around PEGDMA. In addition, the PEGDMA polymer network strongly contributes to maintaining the black phase of γ-CsPbI 3 for more than 35 days in air, and an optimized perovskite film retained ~90% of its initial electrical properties under red, green, and blue light irradiation.
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