On the origin of the Boltzmann distribution

The Boltzmann distribution is used in statistical mechanics to describe the distribution of states in systems with a given temperature. We give a novel characterization of this distribution as the unique one satisfying independence for uncoupled systems. The theorem boils down to a statement about symmetries of the convolution semigroup of finitely supported probability measures on the natural numbers, or, alternatively, about symmetries of the multiplicative semigroup of polynomials with non-negative coefficients.