Preparation of the self-accelerating photocatalytic self-cleaning carboxymethyl cellulose sodium-based hydrogel for removing cationic dyes.
International journal of biological macromolecules(2023)
摘要
Hydrogels loaded with photocatalysts have shown great potential in effectively degrading dye wastewater. In this work, carboxymethyl cellulose sodium-based hydrogels loaded with nitrogen-doped graphene oxide-zinc oxide-zinc peroxide (NGO-ZnO-ZnO2) were synthesized using hydrothermal reaction and in-situ synthesis method. NGO acts as an electron mediator, suppressing the recombination of photoinduced electrons and holes. ZnO2 decomposes to generate hydrogen peroxide (H2O2), promoting a self-enhanced photocatalytic reaction. Carboxymethyl cellulose sodium (CMC) acts as a dispersant, improving the uniformity and stability of NGO-ZnO-ZnO2 within the hydrogel. The results demonstrate that NGO-ZnO-ZnO2 exhibits high photocatalytic degradation efficiency towards methyl orange (MO) (10 mg/L) and rhodamine B (RhB) (50 mg/L), with degradation rates of 99.99 % (200 min) and 99.26 % (160 min), respectively. The carboxymethyl cellulose sodium-based hydrogel achieves a photocatalytic degradation rate of 95.85 % (220 min) for RhB (10 mg/L). After 5 cycles of repeated photocatalytic tests, the degradation efficiency of the hydrogel towards RhB reaches 80.81 %. This work provides a low-cost and convenient method for constructing novel hydrogel carriers with high photocatalytic stability and efficiency.
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