CO oxidation activity of Pt/CeO2 catalysts below 0 °C: platinum loading effects

Applied Catalysis B: Environmental(2021)

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摘要
•Catalyst with 1 wt% of Pt in ceria enables CO oxidation only at T > 100 °C.•Pt/CeO2 catalysts with 8 and 20 wt% Pt loading mediate CO oxidation below 0 °C.•CO oxidation above room temperature occurs with participation of mobile lattice oxygen.•CO oxidation below 0 °C is proposed to occur via weakly co-adsorbed O2 and CO on PtOx clusters.
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关键词
Pt/CeO2,Low-temperature CO oxidation,Single atom,PtOx,DFT calculations
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