Crystal structure of bis(tetramethylthiourea-κS)bis(thiocyanato-κN)nickel(II)
Acta Crystallographica Section E Crystallographic Communications(2020)
摘要
In the course of our investigations regarding transition-metal thiocyanates with thiourea derivatives, the title compound, [Ni(NCS)2(C5H12N2S)2], was obtained. The asymmetric unit consists of one thiocyanate anion and one tetramethylthiourea molecule on general positions, as well as one NiII cation that is located on a twofold rotational axis. In this compound, discrete complexes are formed in which the NiII cations are surrounded by two trans-N-bonding thiocyanate anions as well as two trans-S-bonding tetramethylthiourea molecules within a distorted square-planar coordination geometry. The discrete complexes are linked by pairs of weak C—H⋯S hydrogen bonds between the thiocyanate S and one of the tetramethylthiourea methyl hydrogen atoms into chains along the crystallographic a- and c-axis directions, which are combined into layers parallel to the ac plane. X-ray powder diffraction proves that a pure crystalline phase was obtained and measurements using thermogravimetry and differential thermoanalysis reveal that the compound decomposes at about 408 K, where all tetramethylthiourea molecules are lost.
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关键词
crystal structure,nickel thiocyanate,tetramethylthiourea,discrete complexes,thermal properties
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