A heteroleptic fused bi-cuboctahedral Cu21S2 cluster.

Rhone P Brocha Silalahi,Tzu-Hao Chiu,Hao Liang,Samia Kahlal,Jean-Yves Saillard,C W Liu

Chemical communications (Cambridge, England)（2023）

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摘要

A new dicationic cluster, [CuS{SCNBu}(CPh)], where the Cu21S2 kernel consists of two S@Cu cuboctahedra sharing a triangular Cu face is reported. Its waist part is bridged by three dithiocarbamate ligands, each in a hexaconnective, hexametallic (μ, μ) coordination pattern, an unprecedented feature in Cu nanocluster chemistry.

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