Modulating adsorption of active hydrogen atoms on palladium nanoparticles: Doping ruthenium into metal–organic frameworks for efficient electrocatalytic hydrodechlorination

Chunchao Chen,Liujun Jin,Huilong Dong,Jun Jiang,Hao Feng,Dongyun Chen,Najun Li,Qingfeng Xu,Jianmei Lu

Separation and Purification Technology（2023）

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摘要

•Pd-NiRu-MOF/NF composite electrodes with low noble metal dosage are prepared.•The doping of Ru atoms into Ni-MOF improves the ability to produce active H*.•The adsorption of active H* on Pd is enhanced via doping of Ru atoms.•The EHDC of 2-CP remains effective in natural water or soil washing effluents.

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关键词

Pd-NiRu-MOF/NF,Electrocatalytic hydrodechlorination,Metal–organic frameworks,Chlorophenol

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