{μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)]

Hilario D. Huerta-Zerón,Anke Spannenberg,Matthias Beller,Henrik Junge

IUCrData（2023）

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摘要

The binuclear title compound, [Fe2(C28H48N2O2Si4)(CO)6], consists of two central iron(0) atoms, each of them surrounded by a cyclopentadienone moiety and three carbonyl ligands in a three-legged piano-stool shape. Furthermore, the bis(cyclopentadienone) ligand acts as a bridge between the two metal atoms.Unlabelled Image

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crystal structure,iron carbonyl complex,cyclopentadienone ligand,binuclear complex

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{μ-2,2′-(Ethane-1,2-di­yl)bis­[4,6-bis­(tri­methyl­sil­yl)-1,3-di­hydro­cyclo­penta­[c]pyrrol-5-one]}bis­[tri­carbonyl­iron(0)]

{μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)]