Toward Elimination of Soot Emissions from Jet Fuel Combustion.

Soot from jet fuel combustion in aircraft engines contributes to global warming through the formation of contrail cirrus clouds that make up to 56% of the total radiative forcing from aviation. Here, the elimination of such emissions is explored through N injection (containing 0-25 vol % O) at the exhaust of enclosed spray combustion of jet fuel that nicely emulates aircraft soot emissions. It is shown that injecting N containing 5 vol % of O enhances the formation of polyaromatic hydrocarbons (PAHs) that adsorb on the surface of soot. This increases soot number density and volume fraction by 25 and 80%, respectively. However, further increasing the O concentration to 20 or 25 vol % enhances oxidation and nearly eliminates soot emissions from jet fuel spray combustion, reducing the soot number density and volume fraction by 87.3 or 95.4 and 98.3 or 99.6%, respectively. So, a judicious injection of air just after the aircraft engine exhaust can drastically reduce soot emissions and halve the radiative forcing due to aviation, as shown by soot mobility, X-ray diffraction, Raman spectroscopy, nitrogen adsorption, microscopy, and thermogravimetric analysis (for the organic to total carbon ratio) measurements.