Loss- free tensile ductility of dual- structure titanium composites via an interdiffusion and self- organization strategy

Proceedings of the National Academy of Sciences of the United States of America(2023)

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Abstract
The deformation-coordination ability between ductile metal and brittle dispersive ceramic particles is poor, which means that an improvement in strength will inevitably sacrifice ductility in dispersion-strengthened metallic materials. Here, we present an inspired strategy for developing dual-structure based titanium matrix composites (TMCs) that achieve 12.0% elongation comparable to the matrix Ti6Al4V alloys and enhanced strength compared to homostructure composites. The proposed dual-structure comprises a primary structure, namely, a TiB whisker rich region engendered fine grain Ti6Al4V matrix with a three-dimensional micropellet architecture (3D- MPA), and an overall structure consisting of evenly distributed 3D- MPA "reinforcements" and a TiBw- lean titanium matrix. The dual structure presents a spatially heterogeneous grain distribution with 5.8 p.m fine grains and 42.3 p.m coarse grains, which exhibits excellent hetero- deformation-induced (HDI) hardening and achieves a 5.8% ductility. Interestingly, the 3D- MPA "reinforcements" show 11.1% isotropic deformability and 66% dislocation storage, which endows the TMCs with good strength and loss free ductility. Our enlightening method uses an interdiffusion and self-organization strategy based on powder metallurgy to enable metal matrix composites with the heterostructure of the matrix and the configuration of reinforcement to address the strength-ductility trade-off dilemma.
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Key words
titanium matrix composites (TMCs),dual structure,interdiffusion,hetero- deformation-induced (HDI) hardening,powder metallurgy
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